Beilstein J. Org. Chem.2021,17, 2477–2487, doi:10.3762/bjoc.17.164
, we present a novel synthetic methodology for the photoinduced CuAAC reaction utilizing exfoliated two-dimensional (2D) few-layer blackphosphorus nanosheets (BPNs) as photocatalysts under white LED and near-IR (NIR) light irradiation. Upon irradiation, BPNs generated excited electrons and holes on
molecular properties of the intermediates and final products were evaluated by spectral and chromatographic analyses.
Keywords: blackphosphorus; click chemistry; heterogeneous photocatalyst; near infrared; phosphorene; Introduction
For the last decade, click chemistry has been recognized as an
blackphosphorus (BP), the most stable allotrope of phosphorus, has been shown as a highly efficient photocatalyst possessing superior features in many respects [36][37]. BP, a vital semiconductor 2D material with excellent physicochemical properties such as high carrier mobility, tunable optical
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Graphical Abstract
Figure 1:
Structures of azide and alkyne functional molecules and polymers used in the photoinduced CuAAC rea...